Science 10 · Atoms and the table
The table is the theory
The periodic table looks like a reference chart and is really a compressed theory. Its shape comes from how electrons fill shells, which is why an element's position predicts almost everything it does.
- 1. The words, first
- 2. Why the table looks like that
- 3. Counting the particles
- 4. Metals, non-metals and metalloids
- 5. What costs marks
The words, first
The idea: Three numbers describe an atom, and mixing them up is behind most of the errors in this unit.
| Word | What it means |
|---|---|
| Proton | Positive, in the nucleus. The number of protons is the element. |
| Neutron | Neutral, in the nucleus. Changing the count gives an isotope — the same element, behaving the same way chemically. |
| Electron | Negative, in the space around the nucleus. Chemistry is almost entirely about these. |
| Atomic number | The number of protons. It is what the table is ordered by. |
| Mass number | Protons plus neutrons. |
| Isotope | Atoms of one element with different neutron counts. |
| Valence electrons | The electrons in the outermost shell. They decide how an element reacts, which is why a group behaves alike. |
| Group / family | A column. Same number of valence electrons, so similar behaviour. |
| Period | A row. Properties change steadily across it rather than repeating. |
| Ion | An atom with a charge, because it has lost or gained electrons. Never because it lost protons. |
Why the table looks like that
The idea: The columns are not a filing convention. They are a consequence of shells filling up, and everything else follows.
Electrons occupy shells that hold 2, then 8, then 8 for the first twenty elements. An element's group number tells you its valence electrons, and valence electrons decide reactivity.
- Group 1 has one valence electron to lose, so these metals are very reactive.
- Group 2 has two to lose, forming 2+ ions.
- Group 17 needs one more, so these non-metals are very reactive and form 1− ions.
- Group 18 is already full, which is why the noble gases react with almost nothing.
Trends worth knowing. Reactivity increases down group 1 and up group 17. Both have the same cause: the further the outer electron is from the nucleus, the more easily it is lost — and the harder one is to attract.
A historical note that is really a method note. Mendeleev ordered by atomic mass and had to swap a few pairs to make the families work, and left gaps for elements nobody had found. Moseley later showed the right ordering was by proton count, which removed the exceptions. A theory that predicts missing things is doing more than a chart.
Counting the particles
The idea: Three questions, three places to look.
Protons = atomic number · Neutrons = mass number − atomic number · Electrons = protons, if neutral
Worked. Carbon-14 has 6 protons (carbon's atomic number) and a mass number of 14, so 8 neutrons. It is carbon because of the 6, and it is an isotope because of the 8 — carbon-12 has the same 6 and only 6 neutrons.
Ions. Charge = protons − electrons. Magnesium is in group 2, so it loses two electrons and becomes Mg²⁺. Oxygen is in group 16 and needs two more, so it becomes O²⁻.
The trap. An ion never forms by gaining or losing protons — that would change the element. Only electrons move.
Metals, non-metals and metalloids
The idea: The staircase on the right of the table separates two very different sets of behaviours.
| Metals | Non-metals | |
|---|---|---|
| Where | Left and middle | Upper right |
| Conduct? | Yes, heat and electricity | Mostly not |
| Solid form | Malleable, ductile, shiny | Brittle, dull |
| Electrons | Lose them, forming positive ions | Gain them, forming negative ions |
Elements along the staircase — silicon, germanium — are metalloids, with properties of both. Silicon's halfway conductivity is exactly why semiconductors work.
What costs marks
The idea: Four, and three of them are about which particle moved.
- Saying an ion lost protons. Only electrons move.
- Confusing mass number with atomic mass. Mass number is a count for one atom; atomic mass on the table is an average over isotopes.
- Reading a group number as an ion charge for the transition metals. The pattern works for the main groups.
- Saying electrons are in the nucleus.