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Science 10 · Atoms and the table

The table is the theory

The periodic table looks like a reference chart and is really a compressed theory. Its shape comes from how electrons fill shells, which is why an element's position predicts almost everything it does.

The words, first

The idea: Three numbers describe an atom, and mixing them up is behind most of the errors in this unit.

WordWhat it means
ProtonPositive, in the nucleus. The number of protons is the element.
NeutronNeutral, in the nucleus. Changing the count gives an isotope — the same element, behaving the same way chemically.
ElectronNegative, in the space around the nucleus. Chemistry is almost entirely about these.
Atomic numberThe number of protons. It is what the table is ordered by.
Mass numberProtons plus neutrons.
IsotopeAtoms of one element with different neutron counts.
Valence electronsThe electrons in the outermost shell. They decide how an element reacts, which is why a group behaves alike.
Group / familyA column. Same number of valence electrons, so similar behaviour.
PeriodA row. Properties change steadily across it rather than repeating.
IonAn atom with a charge, because it has lost or gained electrons. Never because it lost protons.

Why the table looks like that

The idea: The columns are not a filing convention. They are a consequence of shells filling up, and everything else follows.

Electrons occupy shells that hold 2, then 8, then 8 for the first twenty elements. An element's group number tells you its valence electrons, and valence electrons decide reactivity.

  • Group 1 has one valence electron to lose, so these metals are very reactive.
  • Group 2 has two to lose, forming 2+ ions.
  • Group 17 needs one more, so these non-metals are very reactive and form 1− ions.
  • Group 18 is already full, which is why the noble gases react with almost nothing.

Trends worth knowing. Reactivity increases down group 1 and up group 17. Both have the same cause: the further the outer electron is from the nucleus, the more easily it is lost — and the harder one is to attract.

A historical note that is really a method note. Mendeleev ordered by atomic mass and had to swap a few pairs to make the families work, and left gaps for elements nobody had found. Moseley later showed the right ordering was by proton count, which removed the exceptions. A theory that predicts missing things is doing more than a chart.

Counting the particles

The idea: Three questions, three places to look.

Protons = atomic number  ·  Neutrons = mass number − atomic number  ·  Electrons = protons, if neutral

Worked. Carbon-14 has 6 protons (carbon's atomic number) and a mass number of 14, so 8 neutrons. It is carbon because of the 6, and it is an isotope because of the 8 — carbon-12 has the same 6 and only 6 neutrons.

Ions. Charge = protons − electrons. Magnesium is in group 2, so it loses two electrons and becomes Mg²⁺. Oxygen is in group 16 and needs two more, so it becomes O²⁻.

The trap. An ion never forms by gaining or losing protons — that would change the element. Only electrons move.

Metals, non-metals and metalloids

The idea: The staircase on the right of the table separates two very different sets of behaviours.

MetalsNon-metals
WhereLeft and middleUpper right
Conduct?Yes, heat and electricityMostly not
Solid formMalleable, ductile, shinyBrittle, dull
ElectronsLose them, forming positive ionsGain them, forming negative ions

Elements along the staircase — silicon, germanium — are metalloids, with properties of both. Silicon's halfway conductivity is exactly why semiconductors work.

What costs marks

The idea: Four, and three of them are about which particle moved.

  • Saying an ion lost protons. Only electrons move.
  • Confusing mass number with atomic mass. Mass number is a count for one atom; atomic mass on the table is an average over isotopes.
  • Reading a group number as an ion charge for the transition metals. The pattern works for the main groups.
  • Saying electrons are in the nucleus.

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