Science 9 · Matter and chemical change
A chemical change makes something new
Ice melting and wood burning both look like change, but only one makes a new substance. Telling the two apart, and then explaining the difference with atoms, is most of this unit — and it is where the safety rules in the science room come from.
- 1. The words, first
- 2. Physical or chemical, and staying safe
- 3. Atoms and the periodic table
- 4. Ionic and molecular compounds, and their names
- 5. Chemical reactions: mass, energy and speed
- 6. What costs marks
The words, first
The idea: Physical versus chemical is the first sorting question in this unit, and almost everything else depends on it.
| Word | What it means |
|---|---|
| Pure substance | One kind of particle: an element (one kind of atom, like aluminium) or a compound (elements chemically joined, like water). |
| Mixture | Substances together but not joined, so they can be separated physically: a solution (salt water) or a mechanical mixture (granola). |
| Physical change / property | A change that leaves the same substance in a new form: melting, dissolving. A physical property can be observed without making a new substance: colour, melting point. |
| Chemical change / property | A change that makes new substances: burning, rusting. Also called a chemical reaction. A chemical property says how a substance reacts: whether it burns, for example. |
| WHMIS 2015 | The labels and pictograms that mark hazardous products in Canadian workplaces and school labs. |
| Atom | The smallest particle of an element: a tiny nucleus of protons (positive) and neutrons (no charge), with electrons (negative) around it. |
| Atomic number | The number of protons. It decides which element an atom is. |
| Group / period | A column / a row of the periodic table. Elements in a group behave alike. |
| Ion | An atom that has gained or lost electrons, so it has a charge. Metals lose electrons (positive ions); non-metals gain them (negative ions). |
| Ionic / molecular compound | Ionic: a metal and a non-metal held together by opposite charges (table salt). Molecular: non-metals sharing electrons, forming molecules (water, sugar). |
| Conservation of mass | In a reaction, the total mass before equals the total mass after. Atoms are rearranged, never created or destroyed. |
| Exothermic / endothermic | Releases energy, so the surroundings warm / absorbs energy, so they cool. |
| Catalyst | Speeds up a reaction without being used up. |
Physical or chemical, and staying safe
The idea: A chemical change makes a new substance. You cannot watch that happen, so you look for its evidence — and avoid the one trap.
Evidence of a chemical change: a new colour; a gas given off when nothing is boiling; a solid forming when two liquids are mixed (a precipitate); heat or light released or absorbed; a change that is hard to reverse.
Worked: a burning candle. Two changes happen at once. Wax melting near the flame is physical — it is still wax, and it hardens again. Wax burning at the wick is chemical — it makes carbon dioxide and water vapour and gives off heat and light. A candle question is usually checking that you name both.
The trap. Boiling water bubbles, and the bubbles are water vapour — still water. Bubbles count as evidence only when a new gas forms, as when baking soda meets vinegar and gives off carbon dioxide.
WHMIS 2015 pictograms are black symbols in a red-bordered diamond; the biohazard one is in a circle.
| Pictogram | Means |
|---|---|
| Flame | Flammable: catches fire easily |
| Flame over circle | Oxidizer: makes other things burn more fiercely |
| Exploding bomb | Explosive, or can react violently |
| Gas cylinder | Gas under pressure |
| Corrosion | Burns skin and eyes, eats metal |
| Skull and crossbones | Small amounts can kill or seriously harm |
| Health hazard | Serious long-term harm, such as cancer |
| Exclamation mark | Less severe harm, such as skin irritation |
| Biohazardous infectious materials | Organisms or toxins that cause disease |
Atoms and the periodic table
The idea: Four models of the atom in about a hundred years. Each kept what the evidence supported and changed what it did not.
| Model | The picture | What led to it |
|---|---|---|
| Dalton, early 1800s | Tiny solid spheres, one kind per element | Compounds always form in fixed proportions |
| Thomson, 1897 | Electrons stuck in a positive sphere, like raisins in a bun | He discovered the electron |
| Rutherford, 1911 | A tiny, dense, positive nucleus in mostly empty space | Most particles fired at gold foil went straight through; a few bounced back |
| Bohr, 1913 | Electrons in fixed energy levels, or shells | Each element gives off only certain colours of light |
protons = atomic number · electrons = protons (neutral atom) · neutrons = atomic mass, rounded − atomic number
Worked. Sodium has atomic number 11 and atomic mass 22.99, so a sodium atom has 11 protons, 11 electrons and 23 − 11 = 12 neutrons. The ion Na⁺ has lost one electron: still 11 protons, now 10 electrons. Chlorine gains one instead, so Cl⁻ has 17 protons and 18 electrons.
Reading the table. Metals, on the left and middle, are shiny good conductors; non-metals, on the upper right, are dull and brittle. Group 1, the alkali metals, form 1+ ions; group 17, the halogens, form 1− ions; group 18, the noble gases, barely react. Science 10 picks this up and explains why the table has this shape.
Ionic and molecular compounds, and their names
The idea: Metal plus non-metal is ionic and named without prefixes. Non-metals only is molecular and named with them.
| Ionic | Molecular | |
|---|---|---|
| Made from | A metal and a non-metal | Non-metals only |
| At room temperature | Solid, high melting point | Solid, liquid or gas; low melting point |
| Solution conducts? | Yes | No |
Ionic names and formulas. Metal first, then the non-metal ending in -ide: NaCl is sodium chloride. The charges in the formula must add to zero:
aluminium oxide: Al³⁺ and O²⁻ → 2 × (+3) = +6 and 3 × (−2) = −6 → Al₂O₃
Some metals, such as iron, form more than one ion, and a Roman numeral says which: iron(III) oxide, Fe₂O₃, is the main substance in rust.
Molecular names. Prefixes count the atoms — mono- 1, di- 2, tri- 3, tetra- 4 — and the first element never takes mono-. CO₂ is carbon dioxide, CO is carbon monoxide, CCl₄ is carbon tetrachloride. Water (H₂O), ammonia (NH₃) and methane (CH₄) keep their common names.
On the test: identify the unknown. A white solid with a very high melting point dissolves, and the solution conducts. It is ionic: its ions are free to move in the water, and moving charges are a current. A sugar solution does not conduct, because sugar dissolves as whole molecules with no charge.
Chemical reactions: mass, energy and speed
The idea: Atoms are rearranged, never lost. What changes is which atoms are joined, whether energy comes out or goes in, and how fast it all happens.
methane + oxygen → carbon dioxide + water
That is combustion: a fast reaction with oxygen that releases heat and light. Corrosion is a slow reaction of a metal with its surroundings; rusting is iron + oxygen, with water present → iron(III) oxide.
Worked: the open-beaker trap. Baking soda and vinegar are mixed in an open beaker on a balance, and the reading falls from 150.0 g to 147.8 g. Nothing was destroyed: 150.0 − 147.8 = 2.2 g of carbon dioxide escaped into the room, and in a sealed bag the reading does not change. When mass seems to change, look for a gas getting in or out. Counting atoms says the same: 2H₂ + O₂ → 2H₂O has 4 hydrogen and 2 oxygen atoms on each side.
Exothermic and endothermic. Burning, rusting and iron-powder hand warmers release energy and feel warm. Baking soda and vinegar is endothermic: the mixture gets slightly colder as it takes in energy. A thermometer that rises during a reaction means exothermic; one that falls means endothermic.
Reaction rate. Particles must collide to react. Warmer particles move faster and collide more often and harder, which is why food keeps in a fridge. A higher concentration puts more particles in the same space. More surface area exposes more of a solid: a log burns slowly, but flour dust in the air can explode. A catalyst speeds things up without being used up — enzymes in your body, platinum in a car's catalytic converter.
On the test. A graph like this brings questions about the investigation as well as the chemistry. Temperature is the manipulated variable and time the responding one, and every tablet must be whole: a broken one has more surface area and would react faster for a reason that has nothing to do with temperature. The toolkit Designing a fair test works through this data in full.
What costs marks
The idea: Six, and three of them are one word swapped for another.
- Calling melting, dissolving or boiling a chemical change.
- Prefixes on an ionic compound. CaCl₂ is calcium chloride, never calcium dichloride.
- Saying mass was lost when a gas escaped.
- Using the atomic mass as the number of protons. Protons come from the atomic number.
- Reading flame over circle as “very flammable.” It means oxidizer.
- Saying a catalyst gets used up.